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Worldwide Refinery Processing Review (Quarterly Issues)

HYDROTREATING, AND REFINERY-PETROCHEMICAL INTEGRATION & CRUDE-TO-CHEMICALS
Publication date:3Q 2019
Item#: B21903

Just Published. Hydrotreating and Refinery-Petrochemical Integration & Crude-to-Chemicals

Hydrotreating

Hydrotreating (HT) is a process that has become synonymous with removing impurities from petroleum feedstocks. By mixing hydrogen and feedstocks under controlled conditions in the presence of a catalyst, contaminants in the form of sulfur-, nitrogen-, and oxygen-containing compounds, as well as metals, can be removed. When the catalyst is designed to remove a specific class of compounds, that fact is reflected in the name of the process, e.g., hydrodesulfurization (HDS), hydrodemetallization (HDM), hydrodenitrogenation (HDN), and hydrodearomatization (HDA)/hydrogenation (HYD).

Hydrotreating is suitable for removing contaminants from feedstreams or product streams. For the feedstocks intended for other refinery processes—catalytic cracking, hydrocracking, catalytic reforming, and isomerization—HT protects the sensitive (and costly) catalysts from contamination. In regards to product streams, refiners rely on HT to perform posttreatment in order to meet mandated specifications such as gasoline benzene, sulfur, and also olefins (for European and Californian standards). HDS of diesel is required to satisfy ultra-low sulfur requirements. To a lesser extent, HT may be used to produce 0.5 wt% sulfur bunker fuel oil for the 2020 International Maritime Organization (IMO) mandate. Furthermore, hydrotreaters play a key role in processing unconventional (resid and renewable) feeds to produce more diesel while helping meet stricter environmental regulations. Hydrotreating is not without drawbacks: the capital investment is significant; operating costs (catalysts and hydrogen) can be high; and product quality may be adversely affected by the potential saturation of aromatics and olefins.

Companies and licensers continue to research on and release highly active HDS catalysts that allow for high HDS conversion while limiting the weighted average bed temperature (WABT) of their reactors. Furthermore, the ongoing shale boom and natural gas supply in the US have led to cheaper hydrogen production for refineries, which has opened the door for increased diesel production by increasing the volume swell of a particular unit. New offerings allow for saturation of aromatics in feeds like LCO in order to decrease diesel density and therefore increase the potential gains of incoming crude. Improvement to diesel quality has also been addressed through hydrodewaxing (HDW), which can improve the cloud point and pour point for better cold flow properties. Numerous companies have released technologies which aim to efficiently and effectively dewax a diesel stream through the use of selective catalysts.

Another challenge for refiners comes from the Tier III gasoline standard, in the US which calls for 10 ppm sulfur in gasoline, which is a third of the previous standard. This change greatly impacts the production of FCC gasoline, as it accounts for around a third of the gasoline blending pool, and is the main contributor of sulfur in the final gasoline product. Different refiners and licensers offer technologies and recommendations when deciding between FCC pretreatment and FCC posttreatment. Both options can reduce sulfur levels to meet the new standards, but at a cost. Pretreatment requires reactors to operate at higher severities, which can decrease catalyst cycles by as much as 40%. Companies are releasing and carrying out research into highly active FCC pretreat catalysts that can produce low-sulfur FCC feeds while maintaining desired cycle lengths. Meanwhile, posttreatment of FCC naphtha can lead to olefin saturation and significant octane loss as a result. New offerings and current research aim to find ways to increase HDS activity while decreasing olefin saturation by making the HDS process more selective.

Additionally, the hydrotreating section features the latest trends and technology offerings, including:

Refinery-Petrochemical Integration & Crude-to-Chemicals

Petrochemicals (PCs) are utilized in various industries for the creation of products such as clothing, housing and construction materials, furniture, cars, toys, packaging, and medical devices. PCs are expected to account for over one third of the global crude demand growth in the next decade and almost half of the growth between 2030 and 2050. As a result, global refineries are starting to take steps to orient output to favor more PCs.

The past several years has seen a boost in interest in refinery and petrochemical integration in order to realize the maximum output of the products of highest value while at the same time achieving adequate production of transportation fuels. This type of integration with a flow of feedstocks, byproducts, and utility (power, steam, water) streams between the two facilities can capitalize on synergies that exist to provide products of high value while increasing the gross margin. Typically, this involves the integration of the refinery with either an olefins complex/steam cracker, an aromatics complex, or both depending on the technical feasibility of such integration and the economic value that it would provide.

Refineries can supply feedstocks such as propane, butane, or naphtha for PCs production. And the product slate within a refinery that is used for integration with petrochemical plants can be expanded by tailoring the hydrocracking unit and/or the FCCU. This can involve the use of catalysts or processes that maximize the yield of hydrocracked naphtha. Also, adjustments can be made in order to boost the BTX composition in FCC naphtha, allowing it to be routed to extraction units for product recovery. The feedstock to the FCCU can be increased to improve petrochemicals production and the FCCU can be modified in order to boost the output of aromatics-rich LCO from which aromatics can be recovered using on-purpose technologies. And, FCC and hydrocracking processes can be used to convert LCO produced from FCC units into aromatics that can be fed to petrochemical plants.

Beyond traditional integrated refinery-petrochemical approaches are new crude-to-chemicals technologies. There are two approaches being pursued that are both being classified as crude-to-chemicals. The first approach bypasses the refinery altogether to achieve the direct conversion of crude in a steam cracker. The second utilizes refinery reconfiguration employing a hydrocracker and other units to produce feeds for a steam cracker and/or aromatics complex. While conventional refineries process a fixed amount of crude to obtain desired fuel yields while utilizing excess naphtha and other streams as feedstocks to produce PCs, a crude-to-chemicals configuration processes an amount of crude that is based on the type and amount of PCs that are to be produced as well as desired transportation fuel yields, if any.

Additionally, the refinery-petrochemical integration & crude-to-chemicals section features the latest trends and technology offerings, including:

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Keywords: hydrogen, hydrotreating, middle distillates, diesel, ULSD, heavy oil, tight oil, fixed-bed, single-stage, two-stage, two-stage with recycle, jet fuel, kerosene, gasoil, gas oil, coker gas oil, coker naphtha, DAO, VGO, HVGO, LCO, resid hydrotreating, renewable hydrotreating, renewable jet fuel, renewable diesel, biodiesel, dewaxing, cold flow properties, cloud point, pour point, cetane, Tier III, gasoline, FCC pretreatment, FCC posttreatment, hydrocracker pretreatment, HDS, hydrodesulfurization, hydrodemetallization, HDM, hydrodenitrogenation, HDN, hydrodearomatization, HDA, hydrogenation, HYD, crude-to-chemicals, direct crude cracking, thermal crude cracking, catalytic crude cracking, aromatics, aromatics production, BTX, benzene, toluene, xylene, meta-xylene, ortho-xylene, para-xylene, catalytic reforming, hydrodealkylation, disproportionation, transalkylation, aromatics recovery/purification, solvent extraction, extractive distillation, adsorption, crystallization, xylenes isomerization, xylenes separation, xylenes purification, ethylene, propylene, butene, butylene, FCCU, on-purpose propylene, PDH, metathesis, MTO, methanol-to-olefins, integrated refinery-petrochemical, steam cracking, naphtha cracking, polymer grade propylene, FCC catalyst, FCC additive, dual riser, downflow reactor, propane-propylene splitter, cryogenic separation, propylene from offgas, alkylation, etherification, heavy olefins, paraffin dehydrogenation, zeolite, ZSM-5, phosphorus additive, membrane separation, absorption